第 27 节
作者:辩论      更新:2021-02-27 01:30      字数:9321
  calculated or obtained。 This is more particularly to be
  noted in the case of black writing inks otherwise
  known as the tanno…gallate of iron inks 'gallic and gallotanic
  acid obtained from nut…galls; sulphate of iron;
  (green copperas) and some gummy vehicle'。
  The variations would appear to be largely due to the
  difference in quality of the gall…nuts; treatment; and
  temperature of the atmosphere; perhaps; however; not
  so much to…day as it was ten or twenty years ago;
  when to make ink of this character boiling processes
  were employed。 Most of them as already stated are
  now 〃cold〃 made。
  Inks of this class consist of a finely divided insoluble
  precipitate suspended in water by the use of gum and
  possessing a slight acidity。
  The requisites of a good black writing ink or
  black writing fluid require it to flow readily from
  the pen; to indicate in a short time a black color
  and to penetrate the paper to an appreciable
  degree; and more important than all the rest; to be of
  great durability。 When kept in a closed vessel no
  sediment of any account should be precipitated; although
  such will be the case in open ink…wells; and
  this the quicker the more the air is permitted to get
  to it。 If it is to be used for record or documentary
  purposes it must not be altogether obliterated if brought
  into contact with water or alcohol; and should depend
  for permanency on its chemical and not on its pigmentary
  qualities。
  The second class; called for distinction 〃chemical
  writing fluids;〃 possesses the same essential ingredients
  to be found in class one; but much less in
  quantity and with some 〃added〃 colored substance
  which I shall term 〃loading;〃 for its real purpose is to
  cheapen the cost of production and not altogether as
  some manufacturers state 〃simply to give them an
  agreeable color。〃
  Previous to the discovery of the soluble anilines;
  logwood; indigo; madder; orchil and other dyeing
  materials were used for a period of some eighty years
  and vanadium for some twenty years (very costly
  at that time); for this purpose; but since 1874; and
  with frequent changes as the newer aniline compounds
  were invented; these by…products of coal…tar; as well as
  logwood; etc。; have been and are to…day employed for
  〃loading;〃 or as the manufacturer expresses; it 〃added
  color。〃 The chemical writing fluids as now prepared;
  yield when first written a blue or green color with a
  tendency to change to black afterwards。 They are
  not as permanent as those of the first class。
  Another black ink not durable; however; is 〃logwood;〃
  its extract is combined with a little chromate
  of potassium and boiled together in water。 It possesses
  its own 〃gum〃 and contains some tannin。 In
  combination with alum and water; it forms a dark
  purple ink。
  The colored writing inks; of which 〃red〃 is the
  more important; are in great number and with hardly
  an exception at the present time; manufactured by
  adding water and water…glass to a soluble aniline red
  color。 Cochineal which was used for red ink formerly
  is now almost obsolete。 Nigrosine; one of the best
  known of them; is much used as a cheap 〃black〃 ink;
  but as it is blue black and never becomes black; it
  really belongs to the family of 〃colored〃 writing
  inks。 They possess an undeserved popularity for they
  flow freely from the pen which they do not corrode;
  nor do they thicken or spoil in the inkwell; they are
  however very 〃fugitive〃 in character and should not
  be employed for record; legal; monetary or other
  documentary purposes。 The indigo and prussian blue
  inks are well known; the former under certain conditions
  a very permanent ink; the latter soon disintegrating。
  Copying inks are of two kinds; one dependent on
  the addition of glycerine; sugar; glucose or like compounds
  to the black writing inks or chemical writing
  fluids heretofore mentioned; which are thereby kept
  in a moist offsetting condition; the other due to the
  solubility of the pigmentary color with water; such as
  the aniline inks which are given more body than
  those for ordinary purposesand the logwoods in
  which the pigment is developed and given copying
  qualities by chemicals; and hence becomes responsive
  to the application of a sheet of paper dampened with
  water。 Copying ink should never be used for
  〃record〃 purposes as it is affected by changes of the
  temperature。
  India ink; sometimes called China ink; or as formerly
  known by the ancients and in classical and later times
  〃Indian ink;〃 is now used more for drawing and engrossing
  than it is for commercial purposes。 It belongs
  to the 〃carbon〃 class and in some form was
  the first one used in the very earliest times。 In
  China it is applied with a brush or pith of some reed
  to the 〃rice〃 paper also there manufactured。 It is
  easily washed away unless bichromate of ammonium
  or potassium in minute quantities be added to it; and
  then if the paper on which it appears be exposed for a
  short time to the action of the actinic rays of sunlight;
  this gummy compound will be rendered insoluble and
  cannot be removed with any fluid; chemical or otherwise。
  It possesses also great advantages in drawing;
  since it acts as a paint; and will give any degree of
  blackness according to the quantity of water mixed with it。
  Secret or sympathetic inks are invisible until the
  writing is subjected to a subsequent operation; such
  as warming or exposing to sunlight。 To further aid
  the object in view; the paper may be first steeped in
  a liquid and the writing only made visible by using
  another liquid which has some chemical affinity with
  the previous one。 The number of this kind were but
  few but have multiplied as chemistry progressed。
  The ancients were acquainted with several modes。
  Ovid indiscreetly advises the Roman wives and maidens
  if they intend to make their correspondence unreadable
  to the wrong persons to write with new milk;
  which when dried may be rendered visible by rubbing
  ashes upon it or a hot iron。 Pliny suggests milky
  juices of certain plants of which there are a considerable
  variety。
  Indelible ink is not used for writing purposes on
  paper; but is found best adapted for marking linen
  and cancellation or endorsing purposes。 It is chiefly
  composed of nitrate of silver preparations; to which
  heat must be applied after it has been dried; or a
  pigment is commingled with the same vehicles used
  in making common printing ink and in its use treated as such。
  Diamonds; gold; silver; platinum and a host of other
  materials are manufactured into ink and are to be
  placed under the head of miscellaneous inks。 They
  are in great number and of no interest in respect to
  ink writing except for engrossing or illuminating。
  Still another ink once held in much esteem and now
  almost obsolete is the so…called 〃safety〃 ink。
  Manufacturers; chemists and laymen in great number
  for many years wasted money; time and energy
  in diligent worship at a secret shrine which could not
  give the information they sought。 A summary of the
  meager and barren results they secured is of little
  value and unimportant。 Hence; there is no REAL 〃safety〃 ink。
  It is true that lampblack (carbon) as made into
  ink; resists any chemical or chemicals; but simple
  water applied on a soft sponge will soon remove such
  ink marks。 The reason for this is obvious; the ink
  does not penetrate the paper。
  〃Safety〃 ink which will not respond to acids may
  be affected by alkalis; or if resisting them separately;
  will yield to them in combination。
  CHAPTER XV。
  OFFICIAL AND LEGAL INK。
  FIRST COMPLETE OFFICIAL INVESTIGATION OF INK IN
  THIS COUNTRYTHE HONOR DUE TO ROBERT T。 SWAN
  OF BOSTONRESUME OF HIS REPORTS TO THE
  LEGISLATURE OF THE STATE OF MASSACHUSETTSTHE
  SWAN LAW ADOPTED IN 1894 BY THE STATE OF
  MASSACHUSETTSUNITED STATES TREASURY DEPARTMENT
  ADOPTS AN OFFICIAL INK IN 1901UNSUCCESSFUL
  ATTEMPT TO SECURE INK LEGISLATION IN THE STATE
  OF NEW YORKCOMMENTS OF THE PUBLIC PRESS OF
  THAT PERIODDIFFERENT WORKS WHICH MORE OR
  LESS DWELL ON THE SUBJECT OF INK FROM 1890 TO
  1900CITATIONS FROM ALLEN'S COMMERCIAL ORGANIC
  ANALYSISREFERENCE TO PAPER ABOUT INK
  READ BEFORE THE NEW YORK STATE BAR ASSOCIATION。
  IT was not; however; until 1891 that the subject of
  the constitution of an enduring record ink received
  the consideration its importance deserved and in this
  the youngest of countries。 To Robert T。 Swan of
  Boston is all honor due for the very unique and
  comprehensive methods adopted in his investigations。
  Appointed 〃commissioner of public records〃 of the
  state of Massachusetts; he has set an example which
  may well be followed by other states; as has been
  done in a lesser degree by Connecticut and ten years
  later by the United States Treasury Department;
  which in this respect is so ably represented in part
  by Dr。 Charles A。 Crampton of Washington; D。